V.2 No 1 |
31 |
Homogeneous 1d resistant line | |
Altenburg in his model considers an 1D chain of equidistant molecules under condition that each of them interacts only with two neighbouring molecules. Naturally he comes to the conventional solution like |
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(41) |
(here Kudryavtcev [18] proceeds from the following relation between adiabatic compressibility of substance and its internal energy U: |
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(42) |
where S is the entropy, p is the
pressure, and Kudryavtcev also supposes a full order of molecules and calculates the derivative of (42) under variation of intermolecular distance along some direction. In fact, he also reduces the problem to the vibration of 1D chain of elastically constrained molecules. Further, supposing that the interior energy of liquid is the potential energy of the intermolecular affection and that when calculating, one can consider only the neighbouring molecules interaction, he yields |
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(43) |
where the relationship of the interaction potential |
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